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93 pages 3 hours read

Sam Kean

The Disappearing Spoon: And Other True Tales of Madness, Love, and the History of the World from the Periodic Table

Nonfiction | Book | Adult | Published in 2010

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Part 2Chapter Summaries & Analyses

Part 2: “Making Atoms, Breaking Atoms”

Chapter 4 Summary: “Where Atoms Come From: ‘We Are All Star Stuff’”

Until the mid-20th century, scientists believed all elements existed since the beginning of time. Keane disabuses us of this notion by explaining that many elements occur through the life cycle of a star.

In 1939 researchers figured out that the sun generates heat by fusing hydrogen atoms into helium; in the 1950s, scientists further proved that heavier elements also are forged inside stars. When stars run out of hydrogen, they fuse helium: “Pretty soon appreciable amounts of lithium, boron, beryllium, and especially carbon accumulate inside stars” (67).

The largest stars keep going, creating all the elements up to iron, number 26. At that point, the stars run out of material, their interior furnaces shut down, and they collapse and explode; in that moment, elements 27 through 92 are created and dispersed. The solar system is created in this way: “About 4.6 billion years ago, a supernova sent a sonic boom through a flat cloud of space dust” (68), blending its elements with the dust and causing ripples that evolve into the sun and planets.

The planet Jupiter is so large that it contains exotic materials, possibly including gigantic diamonds and “metallic hydrogen” (70). Were it ten times larger, Jupiter would be a protostar called a brown dwarf. Most of Jupiter is gas, which contains weather systems.

Much of the heavier elements, such as iron, coalesced into the rocky inner planets, Mercury, Venus, Earth, and Mars. Every star system’s formation is slightly different, so the blend of elements varies among their planets. The heaviest elements are radioactive and break down over time, usually into lead; the present-day ratios of the three forms of lead enable scientists to calculate, through a painstaking process, the age of the earth at 4.55 billion years.

Very little iridium exists on Earth’s surface, but a streak of it can be found in layers of rock 65 million years old. Physicist Luis Alvarez and his son Walter, a geologist, determined that this iridium could only have come from “meteors, asteroids, and comets,” which means that a huge space rock “the size of a metropolis struck the earth sixty-five million years ago” (76). This helps explain why dinosaurs and “75 percent of all species and 99 percent of all living beings died out around that time” (76). According to Kean, geologists discovered “a crater more than one hundred miles wide, twelve miles deep, and sixty-five million years old on the Yucatán Peninsula in Mexico” that fits the bill (76).

Scientists then determined that “massive volcanoes, in India, which were coincidentally erupting before and after the Yucatán impact, helped kill off the dinosaurs” (76). What’s more, scientists discovered “other thin layers of iridium-rich clay—which seemed to coincide geologically with other extinctions” (77). These die-offs occurred at 26-million-year intervals. The iridium layers also contain the element rhenium, which can only come from asteroids. Some scientists once wondered if the sun might have a companion star, Nemesis, that swings close to the solar system, jostling asteroids and comets that then pummel the earth.

Instead, later researchers posited that the sun “is dragged along in the tides of our local spiral galaxy and bobs up and down like a carousel as it drifts,” and that this might cause it to attract space debris, pulling objects toward it at regular intervals, so that some collide with the Earth (79). Kean states, “This theory is far from proved, but if it ever is, we’re on one long, deadly carousel ride through the universe” (79).

Chapter 5 Summary: “Elements in Times of War”

Chemical warfare dates back to ancient Greece (when Spartans tried to smoke out the Athenians with “noxious bundles of wood, pitch, and stinky sulfur” (81)). But chemical attacks remained rudimentary until World War I. The French “lobbed bromine shells at advancing German troops” (82); called lacrimators, these bombs “could incapacitate even a grown man with hot, searing tears” (82).

Meanwhile, in Germany, famed chemist Fritz Haber discovered how to produce large quantities of ammonia (NH3) for use in fertilizer, which revolutionized farming and “likely saved millions from Malthusian starvation” (83). But ammonia also proved useful in bombs (and still does today, such as in the bomb “that Timothy McVeigh used to blow a hole in an Oklahoma City courthouse in 1995” (83)). Haber spearheaded a bromine gas development program, and by 1915 Germany was firing bromine shells at English and Russian troops. Eventually, Haber turned to chlorine, which, like bromine, has seven electrons in its outer shell and is therefore quite caustic, even more so than bromine.

The most deadly of these chemical weapons is mustard gas, which “maimed hundreds of thousands of people and terrorized millions more” (87). Haber won the 1918 Nobel Prize in Chemistry for contributions to food production; he was also charged as a war criminal for his work on mustard gas, what Kean calls “a contradictory, almost self-canceling legacy” (87). Haber, a Jewish convert to Christianity, died in 1934; his prewar invention of the Zyklon B insecticide was used by Hitler to kill Jews in gas chambers, “including relatives of Haber” (87).

Kean’s description of the elements of World War I weaponry continues as he traces the path of molybdenum, a metal used in Germany’s Big Bertha cannons, which were so huge and required so much gunpowder that they quickly overheated and warped. Molybdenum can withstand tremendous heat. But the only source of molybdenum was a mine in Colorado. A German-American mining company hired goons to threaten the miners; owner Otis King sold the mine for a pittance, and Germany got the molybdenum. After the war, King became wealthy by selling molybdenum to Henry Ford for use in his car engines.

Kean explains, “By the time World War II rolled around, molybdenum had been superseded in steel production by the element below it on the periodic table, tungsten” (91), an extremely hard metal with an even higher melting point. Nazis traded looted gold for tungsten to use in “machinery and armor-piercing missiles” (91). The main supplier, neutral Portugal, sold tungsten to both sides.

After World War II, many more metals on the periodic table made their entrances onto the industrial stage. Kean enumerates their many uses: “Gadolinium is perfect for magnetic resonance imaging (MRI). Neodymium makes unprecedentedly powerful lasers” (94). Scandium is added to baseball bats, bike frames, lightweight helicopters, and missile warheads.

Tantalum and niobium are used in cellphones not warfare, but they are nevertheless implicated in conflict, Kean notes. Most tantalum and niobium come from Democratic Republic of the Congo in Africa, where war raged beginning in the 1990s. The two elements were found together as coltan in creek beds, so farmers “abandoned their farms for prospecting” (96). This caused a famine, enriched the militias, and exacerbated the war. In the West, “cell phone makers realized they were funding anarchy” (97), and found another source in Australia. However, in 2006 the European Union “outlawed lead solder in consumer goods, and most manufacturers have replaced it with tin—a metal Congo also happens to have in huge supply” (97). By 2010, five million people had died in the ongoing war. 

Chapter 6 Summary: “Completing the Table … with a Bang”

Kean opens the chapter with a major discovery. In 1913, at the University of Manchester in England, physics professor Ernest Rutherford’s student Henry Moseley fired an electron beam at samples of the various elements; the energy the samples gave off showed that the number of protons in an atom, and not the atom’s total weight, determines its place on the periodic table. This also helped to confirm Rutherford’s theory that every atom contains a central core, called a nucleus, made up of protons and neutrons. Moseley also discovered a number of unknown atoms that helped fill in the table. Scientists raced to fill more gaps. The last missing natural element, promethium, was discovered in 1949.

Next, Kean outlines the discovery in 1932 of a new particle, which solves the puzzle of the atomic nucleus’s mass. The new particle is “the neutral neutron, which adds weight without charge” (105). Some elements have atoms with varying numbers of neutrons; each variety is an isotope. Some isotopes are radioactive: They lose a few protons and neutrons, undergoing “Alpha decay” into lighter elements; others radiate electrons from neutrons in “Beta decay,” which also changes the atomic number of the element (105). The deadliest form of radioactivity, “Gamma decay” (104), is the emission of high-intensity X-rays, “and is today the stuff of nuclear nightmares” (104).

Under certain conditions, radioactive elements such as uranium and plutonium can split, or fission, and release excess neutrons, which slam into nearby atoms and cause them to splinter, too, in “a cascade known as a chain reaction” (106). This process can be harnessed in bombs, but the exact amounts of the materials required, and how they should be blended and shaped, was fiendishly hard to calculate.

During World War II, American scientists used roomfuls of women to do the calculations assembly-line style. The work included numbers for “how the neutron collided with a plutonium atom; whether it was gobbled up; how many new neutrons if any were released in the process; how many neutrons those in turn released; and so on” (108). Then “the women would start over with different numbers” (108). These women were the first “computers” (109). This process replaced time-consuming and expensive experimentation with, in effect, a series of theoretical simulations.

The best results of the simulation process ended up in the successful designs of the first atomic bombs. The process expanded into other domains, becoming known as the Monte Carlo method in honor of early calculations involving card games. The process stimulated the development of early electronic computers that do calculations quickly and efficiently.

Soon, computerized simulations enabled the development of bombs called “‘supers,’ multistage devices a thousand times more powerful than standard A-bombs” (111). These bombs, first detonated in 1952, “used plutonium and uranium to ignite stellar-style fusion in extraheavy liquid hydrogen” (111). Such weapons can be made deadlier still, modified to irradiate landscapes for decades with the highly radioactive isotope Cobalt-60, but their use by major nuclear powers is unlikely “because the conquering army couldn’t occupy the territory” (114). 

Chapter 7 Summary: “Extending the Table, Expanding the Cold War”

In this chapter, Kean explores a theme prevalent throughout the book: the race to scientific discoveries.

Glenn Seaborg discovered plutonium in 1940. After a stint as a Manhattan Project team leader, and assisted by Al Ghiorso starting in 1946, he “discovered more elements than anyone in history and extended the periodic table by almost one-sixth” (118). The two scientists, working at a lab at the University of California at Berkeley, discovered elements 95 through 100: americium (after America), curium (after Marie Curie), berkelium, californium, einsteinium, and fermium (119)—as well as elements 102 and 103: nobelium and lawrencium (“after Berkeley Radiation Laboratory founder and director Ernest Lawrence” (121)). Seaborg won the Nobel Prize, helped found the Pac 10 sports league, and served as an advisor to six presidents.

The Berkeley team’s discovery of element 101 required “a veritable Rube Goldberg machine” to collect and irradiate tiny amounts of einsteinium, followed by a mad dash at night to a distant lab, where a detector pinged 16 times, as individual mendelevium atoms signaled their existence (120). Kean explains, “Ghiorso had wired his radiation detector to the building’s fire alarm” (121), and the pings set off the alarm to cheers.

Meanwhile, Soviet Russia bankrolled science, although Stalinist ideology punished genetic research along with “quantum mechanics and relativity” (124). Some disfavored scientists were forced to work at a highly polluted Siberian nickel mine, helping the search for toxic elements. Stalin’s idea to exterminate bourgeois physicists was rebutted when it’s “pointed out that this might harm the Soviet nuclear weapons program” (125). Stalin relents, saying, “We can always shoot them later” (125).

Physicist Georgy Flyorov, who helped Russia develop its first atomic bomb, beat Berkeley to elements 104 in 1964 and 105 in 1969. Kean states, “Both teams produced element 106 in 1974, just months apart” (127). German researchers got in on the act as well. Decades of arguments about naming rights ensued; in 1996, an international panel finally assigned the names for elements 104 through 109: rutherfordium, dubnium (for the Russian lab where it was discovered), seaborgium (for Seaborg), borhium, hassium, and meitnerium.

Between 1994 and 2009, the Germans discovered elements 110 through 112: darmstadtium, roentgenium, and copernicium. Berkeley, hoping to rekindle its golden age, hired Victor Ninov from the Germans in 1996. Three years later, Ninov announced the discovery of elements 118 and 116, but no other lab could replicate it, and soon the only major discovery out of Berkeley was that Ninov had falsified the data. He was fired. A Russian-American team claimed 118 in 2006, but as of 2010 the claim is still under review. 

Part 2 Analysis

A few more facts may help to flesh out Chapter 4’s description of how the elements are formed:

The universe begins, or so scientists believe, in a Big Bang, when everything that makes up the universe explodes out of an infinitesimally small point. The pressure is so great at first that it’s possible that primordial forces and materials, as yet only theorized by science, exist for a moment. About three minutes later, the two main constituents of atomic nuclei, protons and neutrons, suddenly spew forth in unimaginable profusion.

The density of matter is still so great that some protons and neutrons fuse together to form helium and a couple of other, slightly heavier elements. This is why things got started, not merely with hydrogen, but with a small fraction of heavier elements, especially helium, element number two.

It took about 300,000 years for the universe to expand and cool down enough so that protons and electrons, attracted to each other’s opposite electrical charge, could bind together to form complete hydrogen atoms. When scientists talk about hydrogen, they’re describing an atom that contains a single proton and a single electron. This is the simplest possible atomic combination; basically, a proton by itself is a hydrogen atom with an electric charge, and is sometimes called protium in a nod to its basic makeup.

The point is that, to this day, most of everything in the universe is still very simple stuff, single protons orbited by single electrons, i.e., hydrogen. Out of hydrogen, nearly all the heavier elements are fused together in the blazing hot centers of stars, as described in Chapter 4.

After millions, sometimes billions, of years, enormous clouds of gas that include some of the heavier elements coalesce to form planets orbiting new generations of stars. The atoms, crammed together by gravity, begin more easily to interact and bind together. This is possible because of the complex arrangements of electrons that whirl around each atom, as described in Part 1.

Chapters 5 through 7 deal primarily with what might be called “the elements of war.” Astrophysicist Neil deGrasse Tyson pointed out that much of the funding for science derived from military budgets, since understanding natural law is a kind of power that often proves useful in warfare. Thus, scientists can find themselves quietly complicit in that destructive enterprise. For this reason, the story of Fritz Haber—whose invention of chemical fertilizer and the insecticide Zyklon B helped Germany commit crimes in both world wars—may seem shocking but also is emblematic of the marriage of science and war. On the other hand, sometimes war research begets peacetime benefits, as when the technology of atom bombs is adapted into nuclear power plants, or when the military’s global positioning system gets added to everyone’s cellphones. 

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